Separation of Ammonia from Wastewater by Photocatalyst/Membrane Process Hybrid System

Document Type : Research paper

Authors

1 Department of Chemical Engineering, Faculty of Petroleum and Chemical Engineering, Razi Universirt

2 Faculty of Petroleum and Chemical Engineering, Razi University, Kermanshah, Iran

3 Department of Chemical Engineering, Faculty of Petroleum and Chemical Engineering, Razi University

Abstract

In this research, the performance of photocatalyst/membrane process hybrid system was investigated for the ammonia removal from the wastewater. The prepared membranes were ultrafiltrasion (UF) using the polyethersulfone (PES) by the phase inversion method. Synthetic fumarat alumoxan nanoparticle was used as the additive in the preparation of membrane. The photocatalyst was zinc oxide (ZnO) fixed on a light expanded clay aggregate support named LECA. The effect of the parameters containing amonia initial concetration, nanoparticle content and the treatment process duration on the amonia removal was investigated. The photocatalyst and membrane systems were employed separately and their performance including the flux and rejection was compared with the hybrid system. The results showed that the photocatalyst system was able to remove the amonia at high flux level, well. By consideration of the amonia flux and its removal percentage, the best performance was obtained for the membrane prepared by the PES with 2 wt.% nanoparticle. In hybrid system, firstly, the ammonia was reached to the low concentration and then, the membrane peocess removed this low concentration of ammonia.

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[1]     I.A. Alaton, I.A. Balcioglu, D.W. Bahnemann (2002) "Advanced oxidation of a reactive dyebath effluent: comparison of O3, H2O2/UV-C and TiO2/UV-A processes", Water Research, 36, 1143-1154.
##
[2]     A. Bonmatı́, X. Flotats (2013) "Air stripping of ammonia from pig slurry: characterisation and feasibility as a pre- or post-treatment to mesophilic anaerobic digestion", Waste Management, 23, 261-272.
##
[3]     M. Kaneko, I. Okura (Eds.) (2002) Photocatalysis: Science and Technology, Springer.
##
[4]     J. Zhang, B. Tian, L. Wang, M. Xing, J. Lei (2018) Photocatalysis: Fundamentals, Materials and Applications, Springer.
##
[5]     P. Pichat (2013) Photocatalysis and Water Purification: From Fundamentals to Recent Applications, Wiley-VCH.
##
[6]     T. Zhang et.al (2003) "Photocatalytic decomposition of the sodium dodecylbenzene sulfonate surfactant in aqueous titania suspensions exposed to highly concentrated solar radiation and effects of additives", Applied Catalysis B: Environmental, 42, 13-24.
##
[7]     K.-H. Choo, D.-I. Chang, K.-W. Park, M.-H. Kim (2008) "Use of an integrated photocatalysis/hollow fiber microfiltration system for the removal of trichloroethylene in water", Journal of Hazardous Materials, 152, 183-190.
##
[8]     V.C. Sarasidis, S.I. Patsios, A.J. Karabelas (2012) "Humic Acids Degradation by a Hybrid Photocatalysis-Membrane Process: Effect of UV-A Photon dose on Mineralization Kinetics", Procedia Engineering, 44, 290-292.
##
[9]     F.Martinez et.al (2013) "Coupling membrane separation and photocatalytic oxidation processes for the degradation of pharmaceutical pollutants" Water Reseach, 15, 5647-5658.
##
[10]  J. Grzechulska-Damszel, M. Tomaszewska, A.W. Morawski (2009) "Integration of photocatalysis with membrane processes for purification of water contaminated with organic dyes", Desalination, 241, 118-126.
##
[11]  A.T. Kuvarega, N. Khumalo, D. Dlamini, B.B. Mamba (2018) "Polysulfone/N, Pd co-doped TiO2 composite membranes for photocatalytic dye degradation", Separation and Purification Technology, 191, 122-133.
##
[12]  S. Mozia, A.W. Morawski, M. Toyoda, M. Inagaki (2008) "Effectiveness of photodecomposition of an azo dye on a novel anatase-phase TiO2 and two commercial photocatalysts in a photocatalytic membrane reactor (PMR)", Separation and Purification Technology, 63, 386-391.
##
[13]  N.E. Salim et.al (2018) "Preparation and characterization of hydrophilic surface modifier macromolecule modified poly (ether sulfone) photocatalytic membrane for phenol removal", Chemical Engineering Journal, 335, 236-247.
##
[14]  H. Song, J. Shao, J. Wang, X. Zhong (2014) "The removal of natural organic matter with LiCl–TiO2-doped PVDF membranes by integration of ultrafiltration with photocatalysis", Desalination 344, 412-421.
##
[15]  N.A.M. Nor et.al (2016) "Preparation and performance of PVDF-based nanocomposite membrane consisting of TiO2 nanofibers for organic pollutant decomposition in wastewater under UV irradiation", Desalination 391, 89-97.
##
[16]  B.J. Starr et. al (2016) "Coating porous membranes with a photocatalyst: Comparison of LbL self-assembly and plasma-enhanced CVD techniques", Journal of Membrane Science, 514, 340-349.
##
[17]  L.M. Pastrana-Martinez et. al (2015) "Graphene oxide based ultrafiltration membranes for photocatalytic degradation of organic pollutants in salty water", Water Research, 77, 179-190.
##
[18]  N.H.H. Hairomac, A.W. Mohammad, A.A.H. Kadhum (2014) "Effect of various zinc oxide nanoparticles in membrane photocatalytic reactor for Congo red dye treatment", Separation and Purification Technology, 137, 74-81.
##
[19]  R. Molinariac, L. Palmisano, E. Drioli, M. Schiavello (2002) "Studies on various reactor configurations for coupling photocatalysis and membrane processes in water purification", Journal of Membrane Science, 206, 399-415.
##
[20]  R, Molinari, C. Lavorato, P. Argurio (2017)"Recent progress of photocatalytic membrane reactors in water treatment and in synthesis of organic compounds. A review", Catalysis Today, 281, 144-164.
##
[21]  S. Mozia (2010) "Photocatalytic membrane reactors (PMRs) in water and wastewater treatment. A review", Separation and Purification Technology, 73, 71-91.
##
[22]  X. Zhang, D.K.Wang, J.C.Diniz da Costa (2014) "Recent progresses on fabrication of photocatalytic membranes for water treatment", Catalysis Today, 230, 47-54.
##
[23]  Y.Shavisia, S.Sharifniaa, S.N. Hosseini, M.A. Khadivi (2014) "Application of TiO2/perlite photocatalysis for degradation of ammonia in wastewater", Journal of Industrial and Engineering Chemistry, 20, 278-283.
##
[24]  Y. Shavisi, S. Sharifnia, M. Zendehzaban, M. Lobabi Mirghavami, S. Kakehazar (2014) "Application of solar light for degradation of ammonia in petrochemical wastewater by a floating TiO2/LECA photocatalyst", Journal of Industrial and Engineering Chemistry, 20, 2806-2813.
##
[25]  Z. Mohammadi, S. Sharifnia, Y. Shavisi (2016) "Photocatalytic degradation of aqueous ammonia by using TiO2ZnO/LECA hybrid photocatalyst", Materials Chemistry and Physics, 184, 110-117.
##
[26]  N. Tafreshi, S. Sharifnia, S. Moradi Dehaghi (2017) "Box–Behnken experimental design for optimization of ammonia photocatalytic degradation by ZnO/Oak charcoal composite", Process Safety and Environmental Protection, 106, 203-210.
##
[27]  O. Iglesias, M.J. Rivero, A.M. Urtiaga, I. Ortiz (2016) "Membrane-based photocatalytic systems for process intensification", Chemical Engineering Journal, 305, 136-148.
##
[28]  V. Vatanpour, S.S. Madaeni, L. Rajabi, S. Zinadini, A.A. Derakhshan (2012) "Boehmite nanoparticles as a new nanofiller for preparation of antifouling mixed matrix membranes", Journal of Membrane Science, 401, 132– 143
##
[29]  G. Moradi, S.Zinadinib, L. Rajabi, S. Dadari (2018) "Fabrication of high flux and antifouling mixed matrix fumarate-alumoxane/PAN membranes via electrospinning for application in membrane bioreactors", Applied Surface Science, 427, 830-842.
##
[30]  C. Agarwal, A.K. Pandey, S. Chaudhury, V.T. Aher, A.K. Patra, P.U. Sastry, A. Goswami (2013) "Ionic transport in polyelectrolyte-filled cation-exchange membranes", Journal of  Membrane Science, 446, 125-131.
##
[31]  A.A. Derakhshan, L. Rajabi, H. Karimnezhad (2012) "Morphology and production mechanism of the functionalized carboxylate alumoxane micro and nanostructures", Powder Technology, 225, 156-166.
##
[32]  B. Shahrooiea, L. Rajabi, A.A. Derakhshan, M. Keyhani (2015) "Fabrication, characterization and statistical investigation of a new starch-based hydrogel nanocomposite for ammonium adsorption", Journal of the Taiwan Institute of Chemical Engineers, 51, 201-215.
##