Extraction of propionic acid from water in T-shaped microchannels: effect of mixing channel length and flow rate

Document Type : Research paper

Abstract

In this research, T- shaped microchannels have been utilized for extraction of propionic acid from water using 1-octanol solvent. Effects of mixing channel length and fluid flow rate on the mass transfer characteristics between two phases were investigated. Experiments were performed in four microchannels with ‎lengths of 10, 20, 30 and 40 cm at flow rates‎ between 2 and 16 mL/min. Effect of increasing channel length on the overall mass transfer coefficient, extraction ‎efficiency and pressure drop ‎was studied. Results showed that increasing mixing channel length enhances the mass transfer but it also increases the pressure drop in microchannels. In this regard, performance ratio criterion was defined which its value increased by increasing mixing channel length up to 30 cm and after that decreased. This research suggests that the use of continuous microfluidic systems for extraction of propionic acid from water can be a suitable replacement for conventional batch systems.
 

Keywords

Main Subjects


[1]           W. E. TeGrotenhuis, R. J. Cameron, M. G. Butcher, P. M. Martin, and R. S. Wegeng (1999) "Microchannel Devices for Efficient Contacting of Liquids in Solvent Extraction", Separation Science and Technology, 34, 951-974.
[2]           L. Yang, Y. Zhao, Y. Su, and G. Chen (2013) "An Experimental Study of Copper Extraction Characteristics in a T-Junction Microchannel", Chemical Engineering & Technology, 36, 985-992.
[3]           D. Das, S. Duraiswamy, Z. Yi, V. Chan, and C. Yang (2015) "Continuous Droplet-Based Liquid-Liquid Extraction of Phenol from Oil", Separation Science and Technology, 50, 1023-1029.
[4]           M. Sato, and M. Goto (2004) "Note: Gas Absorption in Water with Microchannel Devices", Separation Science and Technology, 39, 3163-3167.
[5]           J. Tang, X. Zhang, W. Cai , and F. Wang (2013) "Liquid–liquid extraction based on droplet flow in a vertical microchannel", Experimental Thermal and Fluid Science, 49, 185-192.
[6]           L. Zhang, F. Xie, S. Li, S. Yin, J. Peng, and S. Ju (2015) "Solvent extraction of Nd(III) in a Y type microchannel with 2-ethylhexyl phosphoric acid-2-ethylhexyl ester", Green Processing and Synthesis, 4.
[7]           M. N. Kashid, A. Gupta, A. Renken, and L. Kiwi-Minsker (2010) "Numbering-up and mass transfer studies of liquid–liquid two-phase microstructured reactors", Chemical Engineering Journal, 158, 233-240.
[8]           A.-L. Dessimoz, L. Cavin, A. Renken, and L. Kiwi-Minsker (2008) "Liquid–liquid two-phase flow patterns and mass transfer characteristics in rectangular glass microreactors", Chemical Engineering Science, 63, 4035-4044.
[9]           M. N. Kashid, A. Renken, and L. Kiwi-Minsker (2011) "Influence of Flow Regime on Mass Transfer in Different Types of Microchannels", Industrial & Engineering Chemistry Research, 50, 6906-6914.
[10]         R. S. Boogar, R. Gheshlaghi, and M. A. Mahdavi (2013) "The effects of viscosity, surface tension, and flow rate on gasoil-water flow pattern in microchannels", Korean Journal of Chemical Engineering, 30, 45-49.
[11]         J. W. Coleman, and S. Garimella (1999) "Characterization of two-phase flow patterns in small diameter round and rectangular tubes", International Journal of Heat and Mass Transfer, 42, 2869-2881.
[12]         P. Plouffe, D. M. Roberge, and A. Macchi (2014) "Liquid–liquid flow regimes and mass transfer in various micro-reactors", Chemical Engineering Journal, 300, 9-19
[13]         A. Keshav, K. L. Wasewar, and S. Chand (2008) "Extraction of propionic acid using different extractants (tri-n-butylphosphate, tri-n-octylamine, and Aliquat 336)", Industrial & Engineering Chemistry Research, 47, 6192-6196.
[14]         Y. S. Aşçı, and İ. İnci (2009) "Extraction equilibria of propionic acid from aqueous solutions by Amberlite LA-2 in diluent solvents", Chemical Engineering Journal, 155, 784-788.
[15]         A. Keshav, K. L. Wasewar, and S. Chand (2008) "Extraction of propionic acid with tri-n-octyl amine in different diluents", Separation and Purification Technology, 63, 179-183.
[16]         H. Ghanadzadeh, A. Ghanadzadeh, M. Moein, S. Shekarsaraee, and Y. Jamshidi (2012) "Binodal curves and tie line data of the water–propionic acid–iso-butyl acetate at T=(298.2, 308.2, 318.2, and 328.2)K", Thermochimica Acta, 540, 116-122.
[17]         E. İnce, and Y. S. Aşçı (2014) "(Liquid+liquid) equilibria of the (water+carboxylic acid+dibasic esters mixture (DBE-2)) ternary systems", Fluid Phase Equilibria, 370, 19-23.
[18]         Y. Zhao, G. Chen, and Q. Yuan (2007) "Liquid–liquid two-phase mass transfer in the T-junction microchannels", AIChE Journal, 53, 3042-3053.
[19]         N. Assmann, and P. R. von Rohr (2011) "Extraction in microreactors: Intensification by adding an inert gas phase", Chemical Engineering and Processing: Process Intensification, 50, 822-827.
[20]         D. Tsaoulidis, V. Dore, P. Angeli, N. V. Plechkova, and K. R. Seddon (2013) "Dioxouranium(VI) extraction in microchannels using ionic liquids", Chemical Engineering Journal, 227, 151-157.
[21]         S. Eiamsa-Ard (2010) "Study on thermal and fluid flow characteristics in turbulent channel flows with multiple twisted tape vortex generators", International Communications in Heat and Mass Transfer, 37, 644-651.
[22]         M. Rahimi, S. R. Shabanian, and A. A. Alsairafi (2009) "Experimental and CFD studies on heat transfer and friction factor characteristics of a tube equipped with modified twisted tape inserts", Chemical Engineering and Processing: Process Intensification, 48, 762-770.
[23]         Y. Su, Y. Zhao, G. Chen, and Q. Yuan (2010) "Liquid–liquid two-phase flow and mass transfer characteristics in packed microchannels", Chemical Engineering Science, 65, 3947-3956.
[24]         J. Jovanović, E. V. Rebrov, T. A. Nijhuis, M. T. Kreutzer, V. Hessel, and J. C. Schouten (2012) "Liquid–Liquid Flow in a Capillary Microreactor: Hydrodynamic Flow Patterns and Extraction Performance", Industrial & Engineering Chemistry Research, 51, 1015-1026.